The steps below apply to the Apple Watch Series 3 and newer models.
Your Apple Watch auto-connects to networks you have joined before that meet the 802.11b/g/n 2.4 GHz standard (i.e., not compatible with 5 GHz networks).
From the watch face screen, swipe up to access the Control Center.
To determine if you are connected to Wi-Fi, look for the indicator in the upper-left of the Control Center screen.
The Wi-Fi icon (upper-left) is displayed in place of the phone icon.
To disconnect from Wi-Fi, tap the Wi-Fi icon.
The icon dims and your Watch disables all Wi-Fi connections.
The Wi-Fi network disconnected from is not rejoined unless one or more of the following takes place: