Check out the support links for Picture Messaging and how to send a picture message from your phone. Go to VerizonWireless.com and in the Search box in the upper right-hand portion of the page enter the search term "Picture and Video Messaging." There are links there that will show you step-by-step instructions on sending picture messages and answer questions you have about the service.  There is even a demo slideshow you can view www.picture.vzw.com/help/demo.do

Once you are ready to send a picture message, instead of sending it to a ten digit mobile number, you enter your email address in the "To" field.